Sustainable exploitation and safe utilization of biochar: Multiphase characterization and potential hazard analysis

Pyrolysis temperature determines the multiphase (solid and dissolved) structure of biochar (BC). In this study, the temperature-dependent evolution of characteristics and potential hazards of three crop (cotton, alfalfa, and wheat) residue BC were systematically investigated. The results showed that pyrolysis temperature significantly affected the elemental composition and morphology of BC. A higher pyrolysis temperature led to a higher aromatization and graphitization degree of BC. A numerical relationship between pyrolysis temperature and BC surface properties (functional groups, carbonization degree) was established. Pyrolysis temperature controlled the content, composition, and functional group evolution of BC-derived dissolved organic matter. Although the amount of potentially toxic elements (PTEs) in BC was concentrated after pyrolysis, the potentially risk of PTEs significantly decreased. The spin concentration of persistent free radicals in BC prepared at 500 °C was the highest. These findings will hopefully offer comprehensive guidance for sustainable utilization of crop straw and fit-for-purpose exploitation of BC.