An ultrasensitive isoprene gas sensor based on the In₂O₃/MoS₂ nanocomposite prepared by hydrothermal synthesis

Isoprene is one of the specific biomarkers of liver disease in human exhaled gas, which should be detected with a high response at an order of ppb in actual application. In this paper, the heterojunction between n-type In₂O₃ and MoS₂ was proposed to improve the isoprene sensing properties. Both In₂O₃ and MoS₂ were prepared by a hydrothermal method, and nanostructured In₂O₃ flowers and solid micro irregular MoS₂ particles were mixed into the In₂O₃/MoS₂ composite with a mol ratio of 6 : 4. The composite was characterized by EDS and XRD to confirm the element types and crystal types. The isoprene sensor was prepared by dipping the composite suspension on a ceramic substrate integrated with a sensing electrode and heating unit. The testing results of the sensor showed the highest response value of 1.8 to 100 ppb isoprene at 200 °C. Besides, the low detecting limit (less than 5 ppb isoprene) and excellent selectivity are also revealed, showing that the composite can be a good candidate sensing material for isoprene for application in breath analysis.