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Updated: Jan 6, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
Durative Monitoring of Sulfur Hexafluoride Characteristic Gases under Hydrogen Interference Using a Time2Vec-Encoded
Tengfei Li1,2, Yongan Zhang1,2, Hongming Sun1,2
1State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, P. R. China.
Abstract:
Gas-insulated switchgear (GIS) systems extensively employ sulfur hexafluoride (SF6) as an insulating medium and are widely deployed in modern power systems. Under partial discharge (PD) conditions, SF6 decomposes to generate hazardous byproducts such as H2S, SO2, CO, and a certain amount of H2. To mitigate the cross-sensitivity interference among gas sensors when detecting mixed gases, a heterogeneous gas sensor array was designed, integrating three distinct sensor types: metal oxide semiconductor (MOS) sensors, an electrochemical sensor, and a Pd-Au alloy hydrogen sensor. A novel detection framework incorporating a Time2Vec-encoded CNN-Transformer-LSTM deep learning model was proposed for the qualitative identification and quantitative prediction of tetra-component gas mixtures in the SF6 background. The experimental data set was collected over two consecutive days, where the data from Day 1 were augmented to improve the model's generalization performance. Among the three data augmentation strategies evaluated, Gaussian random noise injection yielded superior results in both classification and regression tasks. This approach achieved a classification accuracy of 97.0% and an average F1-score of 97.3%. For concentration estimation, the proposed model attained an average R2 value of 97.6%, with the RMSE for H2S, SO2, CO, and H2 recorded at 0.251, 0.415, 3.023, and 5.701 ppm, respectively. In addition, comparative evaluations with four classical machine learning models─SVM, RF, KNN, and MLP─substantiated the superior accuracy and robustness of the proposed model. Ultimately, the contribution of the Pd-Au alloy hydrogen sensor to the overall performance of the heterogeneous sensor array was comprehensively evaluated. Experimental findings substantiated the sensor's exceptional selectivity for H2 and its pivotal role in effectively mitigating cross-sensitivity effects among the other sensors. The integration of a heterogeneous sensor array with the proposed framework exhibits a strong potential for accurate online monitoring of SF6 decomposition products in GIS systems.
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