Designing Sphere-like FeSe₂-Carbon Composites with Rational Construction of Interfacial Traits towards Considerable...

Due to their low cost and high stability, sodium-ion batteries have been increasingly studied. However, their further development is limited by the relative energy density, resulting in the search for high-capacity anodes. FeSe₂ displays high conductivity and capacity but still suffers from sluggish kinetics and serious volume expansion. Herein, through sacrificial template methods, a series of sphere-like FeSe₂-carbon composites are successfully prepared, displaying uniform carbon coatings and interfacial chemical FeOC bonds. Moreover, benefiting from the unique traits of precursor and acid treatment, rich structural voids are prepared, effectively alleviating volume expansion. Utilized as anodes of sodium-ion batteries, the optimized sample displays considerable capacity, achieving 462.9 mAh g^-1, with 88.75% coulombic efficiency at 1.0 A g^-1. Even at 5.0 A g^-1, their capacity can be kept at approximately 318.8 mAh g^-1, while the stable cycling can be prolonged to 200 cycles above. Supported by the detailed kinetic analysis, it can be noted that the existing chemical bonds facilitate the fast shuttling of ions at the interface, and the enhanced surface/near-surface properties are further vitrified. Given this, the work is expected to offer valuable insights for the rational design of metal-based samples toward advanced sodium-storage materials.