Composite cathode with low-defect NiFe Prussian blue analogue on reduced graphene oxide for aqueous sodium-ion hybrid...

Although sodium-ion hybrid supercapacitor (Na-ion HSC) has attracted great interest, exploitation of suitable cathode materials for reversible Na⁺ insertion reaction remains a challenge. Herein, a novel binder-free composite cathode with highly crystallized NiFe Prussian blue analogue (NiFePBA) nanocubes in-situ grown on reduced graphene oxide (rGO) was fabricated via sodium pyrophosphate (Na₄P₂O₇)-assisted co-precipitation and the subsequent ultrasonic spraying and chemical reduction. Profiting from the low-defect PBA framework and close interface contact of PBA and conductive rGO, the NiFePBA/rGO/carbon cloth composite electrode exhibits a high specific capacitance of 451F g^-1, remarkable rate performance and satisfactory cycling stability in aqueous Na₂SO₄ electrolyte. Impressively, the aqueous Na-ion HSC assembled with the composite cathode and activated carbon (AC) anode manifests a high energy density of 51.11 Wh kg^-1, superb power density of 10 kW kg^-1 and the intriguing cycling stability. This work may open a door for scalable fabrication of binder-free PBA cathode material for aqueous Na-ion storage.