Ionic liquid recovery and recycling via electrodialysis in biomass processing: An economical assessment

Extravagant price and lack of high-efficiency recovery technology limited scale-up utilization of ionic liquids. Ionic liquids recovery with electrodialysis-based techniques has caught wide concern due to membrane-based characteristic. Economical assessment for electrodialysis-based ionic liquid recovery and recycling in biomass processing was performed by determining influence of equipment-related and financial-related factors with sensitivity analysis for each factor. Overall recovery cost of 1-ethyl-3-methylimidazolium acetate, choline acetate, 1-butyl-3-methylimidazolium hydrogen sulphate and 1-ethyl-3-methylimidazolium hydrogen sulfate varied within 0.75-1.96 $/Kg, 0.99-3.00 $/Kg, 1.37-2.74 $/Kg and 1.15-2.89 $/Kg when factors changed within investigated range. Fold of membrane cost, factor of membrane stack cost, factor of auxiliary equipment cost, factor of annual maintenance cost and annual interest rate of loan were positively related with recovery cost. While percentage of annual elapsed time and loan period were negatively correlated with recovery cost. Economical assessment confirmed economic efficiency of electrodialysis for ionic liquids recovery and recycling in biomass processing.