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Related Experiment Video

Updated: Jul 26, 2025

Fabrication of Ti3C2 MXene Microelectrode Arrays for In Vivo Neural Recording
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Memristive Effect in Ti3 C2 Tx (MXene) Polyelectrolyte Multilayers.

Aleksandr Aglikov1, Olga Volkova1, Anna Bondar1

  • 1Infochemistry Scientific Center, ITMO University, Lomonosova str. 9, Saint Petersburg, 191002, Russian Federation.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|June 22, 2023
PubMed
Summary
This summary is machine-generated.

This study explores titanium carbide MXene (Ti3C2Tx) in polyelectrolyte memristors. The PEI-Ti3C2Tx-PSS device shows promising switching characteristics for advanced electronic applications.

Keywords:
DFTMXenememristive effectpolyelectrolyte multilayersself-assembly

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Electronics

Background:

  • Two-dimensional materials called MXenes are gaining attention for electronic applications.
  • Limited research exists on Ti3C2Tx MXene in polyelectrolyte memristors on inert electrodes.

Purpose of the Study:

  • Investigate Ti3C2Tx MXenes synthesized with different delamination agents for memristive devices.
  • Explore characteristics of memristors using MXene-polyelectrolyte multilayers (PEI/PSS).

Main Methods:

  • Synthesis of Ti3C2Tx MXenes using lithium chloride and tetramethylammonium hydroxide.
  • Fabrication and characterization of PEI(MXene)/PSS memristive devices.
  • Density Functional Theory (DFT) calculations for redox potential analysis.

Main Results:

  • PEI(MXene)/PSS memristor shows a voltage threshold (VSET/RESET) of 1.5-2.0 V.
  • Achieved a significant current switching ratio of approximately two orders of magnitude.
  • Observed VSET/RESET difference of ~4 V, supported by DFT calculations.

Conclusions:

  • Ti3C2Tx MXenes are suitable active materials for polyelectrolyte memristors.
  • The PEI-Ti3C2Tx-PSS system demonstrates potential for highly functional, self-assembled memristive devices.
  • This research facilitates the development of memristors for diverse applications.