Converting coastal silt into subgrade soil with biochar as reinforcing agent, CO₂ adsorbent, and carbon sequestrating...

Large amounts of coastal silt produced annually is urgent to be treated with a feasible strategy. This study converted it into subgrade soil by cement solidification for resource utilization. Biochar was used as exogenous additive for enhancing compressive strength of the product, simultaneously achieving carbon sequestration. Three biochars derived from peanut shells (PSBC), cow dung (CDBC) and sewage sludge (SSBC) at 300 °C, 500 °C and 700 °C pyrolysis, were added into raw materials with 1%, 2% and 5%, respectively. All biochars significantly improved the compressive strength of the subgrade soil by 20-110%. Biochar catalyzed cement hydration reactions to produce more Ca(OH)₂, CaCO₃ and calcium silicate hydrates (C-S-H gel). The catalytic capacity of different biochars followed the order of SSBC > PSBC > CDBC. Addition of 2% SSBC500 induced the greatest increase in 28 d-strength from only 1.0 MPa-2.1 MPa, which was due to that 500 °C biochar had a suitable specific surface area and porosity. Biochar facilitated CO₂ capture (absorption) during the hydration reactions at the initial 48 h with 55-70 mg g^-1. The high alkalinity and water holding capacity of biochar contributed to the absorption of CO₂; the high content of minerals in SSBC compared to CDBC and PSBC promoted chemical conversion of CO₂ to carbonate. Besides, the biochar itself as carbon rich material was encapsulated in the subgrade soil, which can be regarded as a long-term carbon sequestration strategy. Carbon budget analysis demonstrated that converting one ton dry silt into subgrade soil with addition of 2% biochar could increase CO₂ sequestration from 11 kg to 36-94 kg. This study proposes a novel strategy of using biochar to strengthen the subgrade soil simultaneously achieve long-term carbon sequestration.