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Are Actinyl Cations Good Probes for Structure Determination in Solution by NMR?

Md Ashraful Islam1, Matthieu Autillo2, Clovis Poulin-Ponnelle2

  • 1Laboratoire de Chimie et Physique Quantiques, CNRS, Université Toulouse III, 118 route de Narbonne, 31062 Toulouse, France.

Inorganic Chemistry
|June 27, 2023
PubMed
Summary

Nuclear Magnetic Resonance (NMR) spectroscopy reveals that plutonium (PuVI) and neptunium (NpV) complexes are ideal for structural analysis in solution. Their magnetic properties remain consistent regardless of equatorial ligands, unlike NpVI complexes.

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