Continuous carbon capture in an electrochemical solid-electrolyte reactor

Electrochemical carbon-capture technologies, with renewable electricity as the energy input, are promising for carbon management but still suffer from low capture rates, oxygen sensitivity or system complexity^1-6. Here we demonstrate a continuous electrochemical carbon-capture design by coupling oxygen/water (O₂/H₂O) redox couple with a modular solid-electrolyte reactor⁷. By performing oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) redox electrolysis, our device can efficiently absorb dilute carbon dioxide (CO₂) molecules at the high-alkaline cathode-membrane interface to form carbonate ions, followed by a neutralization process through the proton flux from the anode to continuously output a high-purity (>99%) CO₂ stream from the middle solid-electrolyte layer. No chemical inputs were needed nor side products generated during the whole carbon absorption/release process. High carbon-capture rates (440 mA cm^-2, 0.137 mmol_CO2 min^-1 cm^-2 or 86.7 kg_CO2 day^-1 m^-2), high Faradaic efficiencies (>90% based on carbonate), high carbon-removal efficiency (>98%) in simulated flue gas and low energy consumption (starting from about 150 kJ per mol_CO2) were demonstrated in our carbon-capture solid-electrolyte reactor, suggesting promising practical applications.