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Updated: Aug 14, 2026

Failure Analysis of Batteries Using Synchrotron-based Hard X-ray Microtomography
Published on: August 26, 2015
Laboratory X-ray computed tomography imaging protocol allowing the operando investigation of electrode material
Krzysztof Dzięcioł1, Yasin Emre Durmus1, Hermann Tempel1
1Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich GmbH, Jülich, Germany.
Abstract:
A robust imaging protocol utilizing laboratory XCT is presented. Hybrid 2D/3D imaging at different scales with real-time monitoring allowed to assess, in operation, the evolution of zinc electrodes within three environments, namely alkaline, near-neutral, and mildly acidic. Different combinations of currents were used to demonstrate various scenarios exhibiting both dendritic and smooth deposition of active material. Directly from radiograms, the volume of the electrode and therefore its growth/dissolution rate was estimated and compared against tomographic reconstructions and theoretical values. The protocol combines simplistic cell design with multiple three-dimensional and two-dimensional acquisitions at different magnifications, providing a unique insight into electrode's morphology evolution within various environments.
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