Structure investigation of light-colored lignin extracted by Lewis acid-based deep eutectic solvent from softwood

Lignin is the most abundant natural phenolic polymer. However, the severe condensations of industrial lignin resulted in an undesirable apparent morphology and darker color, which hindered its application in the field of daily chemicals. Therefore, a ternary deep eutectic solvent is used to obtain lignin with light-color and low condensations from softwood. The results showed that the brightness value of lignin extracted from aluminum chloride-1,4-butanediol-choline chloride at 100 °C and 1.0 h was 77.9, and the lignin yield was 32.2 ± 0.6%. It is important that 95.8% of β-O-4 linkages (β-O-4 and β-O-4') was retained. Lignin is used to prepare sunscreens and is added to physical sunscreens at 5%, with SPF up to 26.95 ± 4.20. Meanwhile, enzyme hydrolysis experiments and reaction liquid composition tests were also conducted. In conclusion, a systematic understanding of this efficient process could facilitate high-value utilization of lignocellulosic biomass in industrial processes.