Low Temperature Chemoresistive Oxygen Sensors Based on Titanium-Containing Ti₂CT_x and Ti₃C₂T_x MXenes

The chemoresistive properties of multilayer titanium-containing Ti₂CT_x and Ti₃C₂T_x MXenes, synthesized by etching the corresponding MAX phases with NaF solution in hydrochloric acid, and the composites based on them, obtained by partial oxidation directly in a sensor cell in an air flow at 150 °C, were studied. Significant differences were observed for the initial MXenes, both in microstructure and in the composition of surface functional groups, as well as in gas sensitivity. For single Ti₂CT_x and Ti₃C₂T_x MXenes, significant responses to oxygen and ammonia were observed. For their partial oxidation at a moderate temperature of 150 °C, a high humidity sensitivity (T, RH = 55%) is observed for Ti₂CT_x and a high and selective response to oxygen for Ti₃C₂T_x at 125 °C (RH = 0%). Overall, these titanium-containing MXenes and composites based on them are considered promising as receptor materials for low temperature oxygen sensors.