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Related Concept Videos

Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

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In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
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Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
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Spin–Spin Coupling: One-Bond Coupling01:17

Spin–Spin Coupling: One-Bond Coupling

1.0K
Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
1.0K
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

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1.1K
Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the...
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¹H NMR: Interpreting Distorted and Overlapping Signals01:02

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Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
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NMR Spectroscopy: Spin–Spin Coupling01:08

NMR Spectroscopy: Spin–Spin Coupling

1.5K
The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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Robust Mutual Synchronization in Long Spin Hall Nano-oscillator Chains.

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Area of Science:

  • Spintronics
  • Condensed Matter Physics
  • Nano-engineering

Background:

  • Spintronic nano-oscillators offer potential for high-quality signal generation.
  • Mutual synchronization of multiple oscillators can enhance performance metrics like coherence and power.
  • Applications in unconventional computing necessitate robust and scalable synchronized oscillator systems.

Purpose of the Study:

  • To investigate the effect of serially connecting spin Hall nano-oscillators on their synchronization properties.
  • To explore the scalability of mutual synchronization in nano-oscillator chains.
  • To quantify the improvements in coherence and peak power with increasing numbers of synchronized oscillators.

Main Methods:

  • Fabrication of spin Hall nano-oscillator chains with up to 50 serially connected nanoconstrictions using W/NiFe, W/CoFeB/MgO, and NiFe/Pt material stacks.
  • Experimental demonstration of mutual synchronization in these chains.
  • Characterization of synchronization robustness, operating frequency, line width, quality factor, and peak power.

Main Results:

  • Achieved robust and complete mutual synchronization of 21 nanoconstrictions at 10 GHz.
  • Demonstrated line widths <134 kHz and quality factors >79,000 for synchronized chains.
  • Observed a quadratic increase in peak power with the number of synchronized oscillators, reaching 400-fold enhancement in long chains.
  • Found that while synchronization persists in chains >21, it becomes less robust, with signal quality plateauing.

Conclusions:

  • Mutual synchronization of serially connected spintronic nano-oscillators effectively boosts coherence and peak power.
  • The number of synchronized oscillators in a chain is critical for performance gains, with optimal performance observed up to 21 units.
  • Longer chains show diminishing returns in signal quality and robustness, indicating limitations in scalability beyond a certain point.