Assessment of soil-soil solution distribution coefficients of global fallout ²³⁷Np and ²³⁹Pu in Japanese upland soils

Neptunium-237 and ²³⁹Pu are important radionuclides in the safety assessment related to geological disposal of radioactive waste because of the possibility of long-term exposure to humans. Mobilities of these radionuclides in the environment are of particular importance for their radiation dose evaluation; therefore, in this study, we have made the assessment of the soil-soil solution distribution coefficient (K_d, L/kg) using global fallout ²³⁷Np and ²³⁹Pu in Japanese upland soils. The K_d values were determined by extracting these radionuclides from 24 soil samples using a laboratory batch method. The desorption K_d values of ²³⁷Np ranged from 3.3 × 10² to 1.0 × 10⁴ L/kg, and their geometric mean (GM) and arithmetic mean (AM) were 1.7 × 10³ L/kg and 2.6 × 10³ L/kg, respectively. The desorption K_d values of ²³⁹Pu were found to vary from 9.4 × 10³ to 7.1 × 10⁴ L/kg, and their GM and AM were 3.3 × 10⁴ L/kg and 4.0 × 10⁴ L/kg, respectively. In Japanese upland soils, the K_d value of ²³⁹Pu was one order of magnitude higher than that of ²³⁷Np.