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Updated: Jul 22, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Linear versus Bent Uranium(II) Metallocenes─A Local Vibrational Mode Study.

Bárbara M T C Peluzo1, Małgorzata Z Makoś1,2, Renaldo T Moura1,3

  • 1Computational and Theoretical Chemistry Group (CATCO), Department of Chemistry, Southern Methodist University, 3215 Daniel Avenue, Dallas, Texas 75275-0314, United States.

Inorganic Chemistry
|July 21, 2023
PubMed
Summary

Researchers explored uranium(II) metallocenes, finding that ligand bulkiness doesn't dictate bent structures. Instead, s/d/f orbital mixing in uranium complexes determines their geometry, not U-ring bond strength.

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