Polymer self-assembly guided heterogeneous structure engineering towards high-performance low-frequency...

Magnetic-dielectric synergy is currently regarded as among the most effective approaches to achieve low-frequency electromagnetic wave absorption (EMA). However, designing and fabricating EMA materials with tunable magnetic-dielectric balance towards high-performance low-frequency EMA remains challenging. Herein, a polymer self-assembly guided heterogeneous structure engineering strategy is proposed to fabricate hierarchical magnetic-dielectric nanocomposite. Polymer assemblies not only can be employed as intermediates to encapsulate metal-organic frameworks and load metal hydroxide, but also that they play a crucial role for the in-situ formation of polycrystalline FeCo/Co composite nanoparticles. As a result, the minimum reflection loss (RL_min) can reach -59.61 dB at 5.4 GHz (4.8 mm) with a 20 wt% filler loading, while the effective absorption bandwidth (EAB, RL_min ≤ -10 dB) is 2.16 GHz, exhibiting excellent low-frequency EMA performance. Systematic investigations demonstrate that hierarchical mesoporous carbon matrix that supports FeCo/Co composite nanoparticles is beneficial for optimizing impedance matching and increasing attenuation capacity. In general, this study opens up new prospects for developing magnetic-dielectric EMA materials using a polymer self-assembly guided heterogeneous structure engineering strategy, which may receive significant attention in future research.