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Updated: Jul 21, 2025

Microbubble Fabrication of Concave-porosity PDMS Beads

Microbubble Fabrication of Concave-porosity PDMS Beads

Published on: December 15, 2015

Polymer Mechanochemistry in Microbubbles.

Mingjun Xuan^1,2, Jilin Fan^1,2, Vu Ngoc Khiêm³

¹DWI - Leibniz-Institute for Interactive Materials, Forckenbeckstr. 50, 52056, Aachen, Germany.

Advanced Materials (Deerfield Beach, Fla.)

|July 26, 2023

Summary

This summary is machine-generated.

This study introduces microbubbles to accelerate polymer mechanochemistry, significantly speeding up the conversion of mechanical energy into chemical bonds. Optimized microbubble properties enhance reaction rates for efficient polymer functionalization.

Keywords:

disulfide mechanophore inertial cavitation microbubbles polymer mechanochemistry ultrasound

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Microfluidic Preparation of Liquid Crystalline Elastomer Actuators

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Published on: May 20, 2018

Area of Science:

Polymer Science
Mechanochemistry
Materials Science

Background:

Polymer mechanochemistry converts mechanical energy into chemical changes by breaking bonds.
Current methods using ultrasonication are slow, requiring long reaction times for significant conversion.
Strategies to accelerate mechanochemical reactions include enhancing molecular reactivity or modifying polymer structure.

Purpose of the Study:

To develop and investigate a novel microbubble system for accelerated polymer mechanochemistry.
To explore the effect of microbubble properties on the efficiency of disulfide bond cleavage.
To optimize microbubble design for maximizing mechanochemical yield.

Main Methods:

Fabrication of microbubbles with a nitrogen gas core and a disulfide-containing polymer shell.
Comparative study of mechanochemical activation using microbubbles, solid particles, and liquid-filled capsules.
Utilizing computational simulations to analyze the relationship between microbubble characteristics and reaction efficiency.
Characterization of microbubble properties such as shell thickness, stiffness, and crosslink density.

Main Results:

Microbubbles significantly accelerated the mechanochemical activation of disulfide bonds compared to other systems.
Computational simulations revealed key parameters influencing mechanochemical yield.
Optimal performance was achieved with thin, flexible shells and low crosslink densities.
Matching the microbubble's eigenfrequency to the ultrasound frequency maximized the reaction rate.

Conclusions:

Microbubble systems offer a highly effective platform for accelerating polymer mechanochemistry.
Tailoring microbubble properties like shell thickness, stiffness, and resonant frequency is crucial for efficient mechanochemical energy transduction.
This approach presents a promising advancement for site-selective polymer functionalization and energy conversion applications.