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Updated: Jul 21, 2025
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Iridium-phosphine ligand complexes as an alternative to rhodium-based catalysts for the efficient hydroformylation of
Chenfei Yao1, Wenjie Xiong1, Haining Sun2
1School of Chemistry and Chemical Engineering, Nanjing University, 163 Xianlin Road, Qixia District, Nanjing 210023, PR China. zbzhang@nju.edu.cn.
Abstract:
Expensive rhodium (Rh)-based catalysts have been widely used for the hydroformylation of propene. To find a cheaper and effective alternative to these Rh-based catalysts, herein, a series of phosphine ligands were used to coordinate with iridium, and their catalytic reactivities for the hydroformylation of propene were systematically investigated in this study. The effects of different phosphine ligands, pressures, temperatures, and catalyst dosages on the hydroformylation of propene were investigated. Tripyridyl phosphine iridium Ir2(cod)2Cl2-P(3-py)3 (Ir(I)-L5) and its derivatives exhibit the highest catalytic reactivity. Surprisingly, the catalytic reactivity of Ir(I)-L5 is higher than that of Rh2(cod)2Cl2-P(3-py)3 (Rh(I)-L5). When the Ir(I)-L5 complex is used as the catalyst, reactions performed in a polar solvent gave higher turnover number (TON) values than those in a non-polar solvent. Up to a TON of 503 can be obtained. Different n-butyraldehyde/iso-butyraldehyde (n/i) ratios can be obtained by adjusting the phosphine ligands or the proportion of gas pressure. The catalyst showed good reusability in five recycling experiments. Furthermore, based on DFT theoretical calculations, a probable reaction mechanism was proposed. It is reliable that an Ir-based catalyst can be considered as a highly effective catalyst for the hydroformylation of propylene with CO.
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