Manipulating Nucleation and Crystal Growth of Inorganic Perovskite Solar Cells

Inorganic metal halide perovskite materials as sunlight absorbers for solar cells exhibit better thermal stability than organic-inorganic hybrid counterparts. Pure cesium lead triiodide (CsPbI₃), with the most suitable band gap, suffers phase instability under an ambient environment. Nucleation and crystal growth are two crucial steps in fabricating a solution-processed perovskite film. A high-quality perovskite film with good morphology makes a significant impact on the efficiency and stability of perovskite solar cells. Dimethylformamide (DMF) is a commonly used aprotic solvent. However, it is difficult to obtain a high-quality inorganic perovskite film using DMF as a single solvent due to its slow evaporation and strong coordination with Pb²⁺. Here, we investigate dimethylacetamide (DMAc)/DMF as a cosolvent to prompt nucleation during the spin-coating process, leading to higher nucleation density and better surface coverage. In addition, we introduce CsBr in dimethylammonium lead triiodide (DMAPbI₃)/CsI precursors to slow down the crystal growth process. CsBr does not increase the film band gap but leads to a pinhole-free film with better crystallinity. Through nucleation and crystal growth engineering, the power conversion efficiency of inorganic perovskite devices is improved to 17.67%, and ambient environment stability is significantly enhanced.