Thermal Conductivity of Covalent-Organic Frameworks
Jinha Kwon1, Hao Ma2,3, Ashutosh Giri4
1Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, New York 14853, United States.
Abstract:
Covalent-organic frameworks (COFs) are a highly promising class of materials that can provide an excellent platform for thermal management applications. In this Perspective, we first review previous works on the thermal conductivities of COFs. Then we share our insights on achieving high, low, and switchable thermal conductivities of future COFs. To obtain the desired thermal conductivity, a comprehensive understanding of their thermal transport mechanisms is necessary but lacking. We discuss current limitations in atomistic simulations, synthesis, and thermal conductivity measurements of COFs and share potential pathways to overcoming these challenges. We hope to stimulate collective, interdisciplinary efforts to study the thermal conductivity of COFs and enable their wide range of thermal applications.
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