Carbon-Doped Co₂MnSi Heusler Alloy Microwires with Improved Thermal Characteristics of Magnetization for...

In the current work, we illustrate the effect of adding a small amount of carbon to very common Co₂MnSi Heusler alloy-based glass-coated microwires. A significant change in the magnetic and structure structural properties was observed for the new alloy Co₂MnSiC compared to the Co₂MnSi alloy. Magneto-structural investigations were performed to clarify the main physical parameters, i.e., structural and magnetic parameters, at a wide range of measuring temperatures. The XRD analysis illustrated the well-defined crystalline structure with average grain size (D_g = 29.16 nm) and a uniform cubic structure with A2 type compared to the mixed L2₁ and B2 cubic structures for Co₂MnSi-based glass-coated microwires. The magnetic behavior was investigated at a temperature range of 5 to 300 K and under an applied external magnetic field (50 Oe to 20 kOe). The thermomagnetic behavior of Co₂MnSiC glass-coated microwires shows a perfectly stable behavior for a temperature range from 300 K to 5 K. By studying the field cooling (FC) and field heating (FH) magnetization curves at a wide range of applied external magnetic fields, we detected a critical magnetic field (H = 1 kOe) where FC and FH curves have a stable magnetic behavior for the Co₂MnSiC sample; such stability was not found in the Co₂MnSi sample. We proposed a phenomenal expression to estimate the magnetization thermal stability, ΔM (%), of FC and FH magnetization curves, and the maximum value was detected at the critical magnetic field where ΔM (%) ≈ 98%. The promising magnetic stability of Co₂MnSiC glass-coated microwires with temperature is due to the changing of the microstructure induced by the addition of carbon, as the A2-type structure shows a unique stability in response to variation in the temperature and the external magnetic field. In addition, a unique internal mechanical stress was induced during the fabrication process and played a role in controlling magnetic behavior with the temperature and external magnetic field. The obtained results make Co₂MnSiC a promising candidate for magnetic sensing devices based on Heusler glass-coated microwires.