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Updated: Jul 19, 2025

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
Interfacial Compatibility of Core-Shell Cellulose Nanocrystals for Improving Dynamic Covalent Adaptable Networks'
Jian Sun1, Mingrui Liang1, Lu Yin1
1Department of Chemical Engineering, Waterloo Institute for Nanotechnology, Centre for Bioengineering and Biotechnology, Institute for Polymer Research, University of Waterloo, Waterloo N2L 3G1, Canada.
Abstract:
The development of polymeric nanocomposites with dynamic covalent adaptable networks and biobased nanomaterials has been a promising approach toward sustainable advanced materials, enabling reprogramming and recycling capabilities. Herein, a core-shell nanohybrid of functionalized cellulose nanocrystals (CNCs) is explored to provide crucial interfacial compatibility for improving the covalent adaptable networks of epoxy-thiol vitrimers in fracture resistance. The poly(ε-caprolactone) (PCL) shells grafted from CNC surfaces can be cross-linked with the covalent adaptable networks via a hot-pressing transesterification process. According to the additive concentration and annealing temperature, the stress relaxation behavior of nanohybrid vitrimer composites can be effectively regulated by the core-shell PCL-grafted CNC (CNC-PCL) nanohybrids from a dispersed to cross-linked interaction. The addition of 15 wt % of the core-shell CNC-PCLs exhibits the reinforced improvement of nanohybrid vitrimer composites in the average Young's modulus of 2.5×, fracture stress of 5.4×, and fracture strain of 2.0×. The research findings might have profound implications for developing synergistic interfacial compatibility between dynamic vitrimer networks and functional nanoparticles for advanced polymeric nanocomposites.
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