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Published on: December 16, 2022
A Biaryl-Cyclohexenone Photoelectrocyclization/Dearomatization Sequence to Substituted Terpenes
K S Satyanarayana Tummalapalli1, Xuchen Zhao1, Jon D Rainier1
1Department of Chemistry University of Utah Salt Lake City, UT 84112.
Abstract:
Described here is the development of sequential cross-coupling, photoelectrocyclizations, and reductive dearomatizations of biaryl cyclohexenones as a means of synthesizing terpene skeletons. This methodology promises to provide insight that will enable us and others to use this approach to generate a variety of biologically active small molecules, including members of the abietane and morphinan skeletons.
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