Pickering phase change slurries

Phase change slurries (PCS) have emerged as a promising class of oil-in-water emulsions for energy applications, but stability remains an issue. Pickering phase change slurries (PPCS) stabilized solely by nanoparticles could offer enhanced stability. We hypothesize that stability in PPCS can be achieved by tuning environmental variables of salinity and temperature.

A paraffin-based PPCS stabilized using fumed silica nanoparticles was developed and assessed under varying NaCl concentrations (up to 150 mM) and temperatures (up to 70 °C). Extended-DLVO modeling, confocal, and cryogenic electron microscopy analyzed the silica-paraffin interactions. Rheological experiments examined the impact of effective volume fraction, thermal expansion, and salinity on the viscosity and shear stability of PPCS. The stability of the resulting formulation was assessed under high pressure and temperature conditions.

Increased salinity did not change the packing density of the silica at the oil-water interface (82% ± 6%) but did increase the adsorbed layer thickness and network formation, enhancing the formulation's resistance to shear-induced instability. A critical volume fraction of 0.51 ± 0.01 was identified, beyond which viscosity increased significantly. The resulting formulations remained stable under high pressures and temperatures, regardless of salinity. These findings offer insights into the variables affecting PPCS properties, assisting in designing stable PPCS formulations for diverse applications.