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Updated: Jul 18, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Satellite Red Emission from a Single Green-Emissive MnBr42- Tetrahedron in Soft Hybrid Single Crystals
Shuai Zhang1,2, Lei Wang1, Yilan Wang3
1State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, 510641 Guangzhou, China.
Abstract:
Photoinduced self-trapped exciton emission is common in soft matter metal halide semiconductors, whereas analogous phenomena in metal halide insulators with localized emitting centers and delayed satellite emission have rarely been identified. In this study, a new zero-dimensional Mn(II) hybrid of [3DPTPP]MnBr4 (3DPTPP = (3-(dimethylamino)propyl)(triphenyl)phosphonium) with only one crystallographic Mn2+ site but dual emission is reported. The delayed red emission (∼630 nm) is successfully assigned to a satellite of the green-emissive (∼530 nm) MnBr42- tetrahedron shifted by N-H vibration (∼2500 cm-1), directly evidenced by the Raman spectra and further supported by density functional theory calculation. The photoluminescence decay curves demonstrate their same origin, but the red emission exhibits a delayed process. The temperature- and pressure-dependent PL spectra, temperature-dependent distortion of the MnBr42- tetrahedron, and light polarization spectra confirmed the consistency and distinctness of the dual emission. This study will inspire further research on self-trapped optoelectronic processes in soft metal halides.
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