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Formation and Characterization of Stable TiO2/CuxO-Based Solar Cells
Grzegorz Wisz1, Paulina Sawicka-Chudy1, Maciej Sibiński2,3
1Institute of Materials Engineering, College of Natural Sciences, University of Rzeszow, Pigonia 1, 35-310 Rzeszow, Poland.
Materials (Basel, Switzerland)
|August 26, 2023
Summary
Metal oxide semiconductors like TiO2 and CuxO show promise for photovoltaic cells. This study details manufacturing and characterization of these thin-film solar cells, achieving up to 0.01% efficiency.
Area of Science:
- Materials Science
- Renewable Energy
Background:
- Growing energy demand necessitates efficient solar energy solutions.
- Metal oxide semiconductors (MOS) offer advantages like availability and low cost.
- Titanium dioxide (TiO2) and copper oxides (CuxO) are promising MOS for photovoltaics.
Purpose of the Study:
- To detail the manufacturing of a complete photovoltaic structure using MOS.
- To characterize the morphology, structure, composition, and photovoltaic parameters of fabricated films.
- To analyze the junction operation based on electrical characteristics.
Main Methods:
- DC magnetron sputtering for film deposition.
- Scanning Electron Microscopy (SEM) for morphological analysis.
- Current-Voltage (I-V) measurements for photovoltaic performance evaluation.
Main Results:
- Uniform film deposition observed via SEM, with conglomerate sizes ranging from 20-530 nm.
- Film thickness varied from 318 to 1654 nm.
- Photovoltaic behavior confirmed, with open-circuit voltage (Voc) up to 300 mV and short-circuit current density (Jsc) up to 7.26 µA/cm³.
- Maximum power conversion efficiency achieved was 0.01%.
Conclusions:
- The study successfully manufactured and characterized MOS-based thin-film solar cells.
- The results demonstrate the potential of TiO2 and CuxO for effective photoconversion.
- Further optimization is needed to improve the efficiency of these photovoltaic devices.

