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Updated: Jul 18, 2025

Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Nitrogen-rich carbon composite fabricated from waste shrimp shells for highly efficient oxo-vanadate
Irshad Ibran Shahib1, Jerosha Ifthikar1, Siqi Wang1
1Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, PR China.
Abstract:
Protein, calcium carbonate, and chitin are abundant in shrimp shells. In this study, chemical treatment followed by hydrothermal carbonization was used to synthesize the nitrogen-rich hydrochar (HSHC) from shrimp shells. The untreated hydrochar exhibited a higher amount of calcium (25.37%) and less amount of nitrogen (2.68%) with alkaline pH (9.1). Interestingly chemical pre-treatment on shrimp shells boosted the nitrogen content to 6.81% and eliminated the calcium while controlling the pH to 6.4, which was beneficial for oxo-vanadate removal. The HSHC achieved vanadium(V) adsorption capacity of 21.20 mg/g at an optimal solution pH of 3.0, whereas the pristine hydrochar performed poorly (0.66 mg/g). The abundance of oxygen and nitrogen-based functional groups that developed through the chemical treatment resulted in improved adsorption coupled reduction performance of HSHC. This study proposed an inexpensive and environmentally friendly method for converting waste shrimp shells into value-added adsorbent.
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