Related Experiment Video
Updated: Jul 17, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Hg2+ detection and information encryption of new [1+1] lanthanide cluster
Xiaobo Yu1, Wenting Chang1, Ziyan Cai1
1Department of Chemistry and Chemical Engineering and Nanofiber Engineering Center of Jiangxi Province, Jiangxi Normal University, Nanchang, 330022, PR China; National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Nanchang, 330022, PR China.
Abstract:
The sensing of heavy metal ion and information encryption are two very important research areas. Therefore, developing multi-functional materials capable of sensing heavy metal ions and encrypting information is highly important. In this work, three [1 + 1] lanthanide clusters [Ln(TFBA)3(dmp) (H2O)2]2 (Ln = Tb3+Tb1+1, Eu3+Eu1+1, Gd3+Gd1+1, HTFBA = 2,3,4,5-tetrafluorobenzoic acid, dmp = 4,7-dimethyl-1,10-phenanthroline) were designed and synthesized. Among them, Tb1+1 shows excellent luminescence sensing towards Hg2+ (Ex = 350 nm, Em = 545 nm). Results demonstrates the sensing with high selectivity, strong anti-interference, 20-s response time, high accuracy, excellent linear relationship in 0-20.0 μM, and a very low limit of detection (0.02 ppb). Furthermore, paper strips based on Tb1+1 is fabricated for visual detection of Hg2+ in real samples of tap water, lake water, human urine, and human serum. More interestingly, a new method for confidentiality of information is realized through multi-color anti-counterfeiting patterns with the [1 + 1] lanthanide cluster ink, based on the luminescence "on-off" sensing towards Hg2+.
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
02:42Valence Bond Theory
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
01:07Nuclear Overhauser Enhancement (NOE)
04:00Periodic Classification of the Elements