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Updated: Jul 16, 2025

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration
Published on: March 29, 2019
Glycerol photocatalytic oxidation to higher value-added compounds via bismuth oxyhalide photocatalysts
Paphada Limpachanangkul1, Prathana Nimmmanterdwong2, Licheng Liu3
1Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Pathumwan, Bangkok, 10330, Thailand.
Abstract:
Bismuth oxyhalides (BiOX) including BiOCl, BiOBr, and BiOI, were well synthesized using solvothermal technique and then used in the aqueous phase photooxidation of glycerol as a catalyst. The as-synthesized BiOBr could achieve the highest glycerol transformation of around 85.6% in 8 h under ultraviolet light (UV) irradiation among as-synthesized BiOXs. Moreover, the BiOBr/TiO2 heterojunction was also prepared through an ethylene glycol-assisted solvothermal process. This new BiOBr/TiO2 heterostructure exhibited excellent photocatalytic activity (97.4%) for the oxidation of glycerol compared with pure BiOBr (74%) under ultraviolet light irradiation at 6 h. This obtained behavior was confirmed by more produced OH• radicals of BiOBr/TiO2.
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