A poly(o-phenylenediamine) coated aluminum garter spring micro-solid phase extractor for pyrethroids in chili

An aluminum garter spring coated with poly(o-phenylenediamine) (PoPD) was developed as a sorbent for the micro-solid phase extraction of seven pyrethroids, bifenthrin, fenpropathrin, lambda-cyhalothrin, cyfluthrin, permethrin, cypermethrin and deltamethrin from fresh chili, chili flakes, and curry pastes. The extraction was qualified and quantified by a gas chromatograph coupled with an electron capture detector. Under optimum conditions, the linearity was at a concentration range of 10-3000 µg kg^-1. The limits of detection and limits of quantitation of 9.3 to 34.2 μg kg^-1, and 11.8 to 48.6 μg kg^-1, respectively, were obtained with good sorbent-to-sorbent reproducibility, and outstanding reusability. When applied to determine the seven pyrethroids in chili samples, some pyrethroids were detected up to 30.3 ± 1.2 μg kg^-1. This proposed method is simple, with potential applications in the trace analysis of other compounds.