Novel Design of Perovskite-Structured Neodymium Cobalt Oxide Nanoparticle-Embedded Graphene Oxide Nanocomposites as...

In recent years, electrochemical supercapacitors are expected to represent the future of energy storage device technology. Specifically, the excellent electrochemical performance with long cycle life, high energy, and power density is considered an essential criterion for commercial applications. Herein, we constructed a novel composite of neodymium cobalt oxide-encapsulated graphene oxide nanocomposite (NCO/GO) via a simple and robust method for a symmetric supercapacitor (SSC) device. The prepared samples were securitized by X-ray diffraction, Fourier transform infrared spectroscopy, Raman, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and Brunauer-Emmett-Teller analysis. The as-synthesized NCO/GO is deposited on nickel foam (NF) and used as a supercapacitor electrode (NCO/GO/NF), which exhibits superior specific capacitance (C_s) of 1080.92 F g^-1 at 1 A g^-1 and fantastic cycling life with ∼89.42% retention after 10,000 cycles at 10 A g^-1 in 1.0 M KOH aqueous electrolyte. A tremendous electrochemical performance of the hybrid nanocomposite electrode is obtained from the good redox activity and synergistic effects of the NCO spherical-like nanoparticles combined with the GO nanosheets. Furthermore, the assembled SSC device delivers significantly enhanced power density (932.93 Wh kg^-1) and energy density (210.42 mWh kg^-1). Moreover, the SSCs exhibit excellent cycling stability with ∼82.19% capacity retaining over 10,000 charge/discharge cycles. Remarkably, a 1.8 V red light-emitting diode (LED) can be lit up for more than 10 min by series connection SSCs. Thus, the obtained results indicated that the NCO/GO/NF//NCO/GO/NF symmetric device has a robust and cost-effective electrode material for high-performance supercapacitor systems.