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Updated: Jul 16, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
A Tb3+ ion encapsulated anionic indium-organic framework as logical probe for distinguishing quenching Fe3+ and Cu2+
Bin Wang1, Wei Zheng2, Jiashang Chen1
1Center of Advanced Optoelectronic Materials and Devices, Key Laboratory of Novel Materials for Sensor of Zhejiang Province, College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China.
Abstract:
We successfully synthesized a stable anionic microporous metal-organic framework (MOF) HDU-1 ([Me2NH2]2In2[(TATAB)4(DMF)4](DMF)4(H2O)4) and constructed a fluorescent probe Tb@HDU-1 by an exchange strategy. Because of its suspension distinct fluorescent response of Tb(III) characteristic transition and ligand emission, the Tb@HDU-1 can be used as fluorescent probe for sensing towards Fe3+ and Cu2+ ions. It is surprising that Tb@HDU-1 is used as a ratiometric fluorescent probe for Cu2+ ions while only single peak detection for Fe3+ ions, which describes a particular rare example of a sensor based on Ln-MOFs to distinguish quenching Fe3+ and Cu2+ ions. Hence we designed a molecular logic gate device for making the distinction of Fe3+ and Cu2+ ions more clearly and appropriately. In addition, the different quenching effect between Fe3+ and Cu2+ ions may be ascribed to the differences of competitive absorption and interaction between frameworks and metal ions.
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