Tailoring the performance of composite PEI nanofiltration membranes via incorporating activated cyclodextrins

Cyclodextrins (CDs) with unique cavity structures have been used as materials for nanofiltration membrane fabrications. In the present work, the activated CD (O-CD), oxidated by NaIO₄, and polyethyleneimine (PEI) were co-deposited on a hydrolyzed polyacrylonitrile support, post-treated by glycerol protection and heating treatment, to prepare nanofiltration membranes with low molecular weight cut-off (MWCO). As the cavities in CD present and the aldehyde groups introduced after oxidation, the O-CDs were expected to crosslink the PEI layer and provide extra permeating channels. The filtration experiments showed that the incorporation of O-CDs improved the permeances of the O-CD-PEI/HPAN nanofiltration membranes. The performance can be tailored by the control of the loading or the oxidation degree of the O-CD. At optimal conditions, the permeance increment was nearly double (from 9.2 to 21.1 Lm^-2·h^-1·bar^-1). While the selectivity was without significant sacrifice, the rejection of PEG 200 remained around 90%. Meanwhile, the membrane stability was demonstrated by pro-longed filtratiing a PEG 200 aqueous solution. The constant permeance and rejection confirmed the O-CD-PEI/HPAN membranes were stable. The incorporation of activated CD in PEI offers a facile strategy to promote the permeance of PEI-based membranes.