Bio-mimetic selectivity in Hg²⁺ sensing developed via electro-copolymerized PEDOT and benzothiazole-Au nanoparticles...

To eliminate the potential health risks of mercury, development of stable and selective mercury sensor with high sensitivity is the need of the hour. To address this, a novel PEDOT-AA-BTZ-Au-based Hg²⁺ selective, hybrid electrochemical sensor has been designed by following a simple protocol for electrode fabrication. The electrode was designed by carefully optimizing the onset oxidation potential of supramolecule 2-(anthracen-9-yl)benzo[d]thiazole (AA-BTZ) and conducting polymer poly-(3,4-ethylenedioxythiophene) (PEDOT), using copolymerization approach followed by dropcasting of gold nanoparticles (AuNPs). The designed electrode offered synergistic effects thus augmenting the electrical conductivity and adsorption capacity as depicted by its porous surface morphology. The highly sensitive analytical signal was generated by sulphur pockets present in AA-BTZ and PEDOT conducting framework. This is further complemented by the selectivity offered by the soft interactions between AuNPs and Hg²⁺ resulting in a low detection limit of 0.60 nM. The prepared system was further utilized for sensing Hg²⁺ ion in real systems including lake water and cosmetic samples. Low interference from other ions and better reproducibility further established the suitability of the designed transducer system for future on-site sensing.