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Variational quantitative phase-field modeling of nonisothermal sintering process.

Timileyin David Oyedeji1, Yangyiwei Yang1, Herbert Egger2

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This study introduces a new variational phase-field model for nonisothermal sintering, overcoming artificial interface effects and ensuring thermodynamic validity for accurate pore-structure evolution modeling.

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Area of Science:

  • Materials Science
  • Computational Materials Science
  • Thermodynamics

Background:

  • Phase-field modeling is crucial for simulating sintering but faces challenges with quantitative accuracy and artificial interface effects.
  • Existing models struggle with the asymmetric mass and thermal properties at solid-pore interfaces in nonisothermal sintering.
  • Prescribed anti-trapping terms can compromise the thermodynamic variational nature of models.

Purpose of the Study:

  • To develop a variational and quantitative phase-field model for nonisothermal sintering processes.
  • To address artificial interface effects and ensure thermodynamic validity.
  • To accurately capture the interplay between mass/thermal transfer and grain growth.

Main Methods:

  • Developed an extended non-diagonal phase-field model for nonisothermal sintering.
  • Incorporated naturally cross-coupled terms between conserved (mass, thermal) and non-conserved (grain growth) kinetics.
  • Utilized asymptotic analysis to verify the elimination of interface artifacts and preservation of thermodynamic equilibrium.
  • Introduced an anisotropic interpolation scheme for kinetic mobilities.

Main Results:

  • The developed model eliminates interface artifacts without altering thermodynamic equilibrium.
  • Cross-coupling terms are shown to be crucial for accurate simulation of sintering.
  • Demonstrated the direction-dependent nature of trapping effects and surface diffusion.
  • Anisotropic interpolation of kinetic mobilities is essential for capturing thermal-microstructural evolution.

Conclusions:

  • The new variational phase-field model provides a quantitatively valid approach for nonisothermal sintering.
  • The model accurately captures complex thermal-microstructural evolutions by addressing interface phenomena.
  • This work advances the application of phase-field modeling in materials processing.