Related Experiment Video
Updated: Jul 16, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Regulating the Content of Donor Unit in Donor-Acceptor Covalent Triazine Frameworks for Promoting Photocatalytic H2
Wei He1, Jing Zhou1, Wenhua Xu1
1Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710069, P. R. China.
Abstract:
Using their own triazine groups as natural receptors, the introduction of various donor units to construct donor-receptor configuration in covalent triazine frameworks (CTFs) has been shown to be an effective strategy to improve photocatalytic activity. In this work, the effect of donor unit content (D-content) on the photoelectric properties and photocatalytic activity of CTFs was thoroughly investigated. Four analogous CTFs with different D-content have been rationally designed and synthesized, in which the bithiophene (Btp) as the donor unit and triazine as the acceptor unit. And CTF-Btp with the highest D-content showed the best photocatalytic activity. The experimental and theoretical results indicated this improvement is attributed to stronger visible light absorption capacity and higher photoinduced charge carrier separation efficiency. This study elucidates the relationship between the structural features of CTFs with varying D-content and their photocatalytic activity, offering a promising strategy for developing efficient photocatalysts.
More Related Videos
Related Concept Videos
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Cycloaddition Reactions: MO Requirements for Photochemical Activation
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...

