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Harvesting Solar Energy by Means of Charge-Separating Nanocrystals and Their Solids
Published on: August 23, 2012
CdTe QD-decorated GO nanosheet heterojunction for efficient photocurrent generation and photocatalytic activity
Sumathi Subramanian1, Sasikala Ganapathy1, Suguna Subramanian1
1Crystal Growth Centre, UGC-National Facility, Anna University, Chennai-600 025, Tamil Nadu, India. sasikalaganapathycgc@gmail.com.
Abstract:
Cadmium telluride quantum dot (CdTe QD)-decorated graphene oxide (GO) nanosheets are promising heterojunctions for the environmental remediation of organic pollutants in water. However, assembling these two materials is a challenge. For this purpose, we have developed a one-step approach for the decoration of QDs onto the surface of GO nanosheets/intercalation of QDs into GO nanosheets through self-assembly, resulting in the formation of sandwiched hybrid heterojunctions. After synthesis, the samples were analysed for variations in their structural, morphological, compositional, optical and photoelectrochemical characteristics using various analytical tools. Interlinking QDs and GO nanosheets enhanced the photocurrent generation (∼5.8 μA cm-2), resulting in faster electron transfer by delaying the decay time (58.25 ms). A higher rate constant value (k = 0.135 min-1) was obtained for degrading 93% MB dye in 20 min. This work demonstrates a cost-effective strategy for constructing CdTe QDs/GO nanosheet hybrid heterojunctions for potential application in the field of photocatalysis.

