Plasma-catalyzed combined dynamic wave scrubbing: A novel method for highly efficient removal of multiple pollutants...

In this study, we developed a novel approach combining a non-thermal plasma system with M(Ce, Cu)-Mn/13X oxidation and post-dynamic wave wet scrubbing technologies, for effectively removing multiple pollutants from flue gases. Experimental results demonstrated that the plasma coupled with post-dynamic wave wet scrubbing achieved impressive synergistic removal efficiencies of 98% for SO₂, 50.9% for NO, and 51.3% for Hg⁰ in flue gas. Through the use of M(Ce, Cu)-Mn/13X catalysts synthesized via the co-precipitation, the oxidation efficiency of the system is significantly enhanced, with synergistic removal efficiencies reaching up to 100% for SO₂, 98.7% for NO, and 96% for Hg⁰. Notably, (Ce-Mn)/13X exhibited superior catalytic activity, the results are supported by comprehensive sample characterization, DFT mechanistic analysis, and experimental validation. Additionally, we elucidated the plasma oxidation mechanism and the working principles of the M(Ce, Cu)-Mn/13X loaded catalysts. This innovative technology not only facilitates pollutant oxidation but also ensures their complete removal from flue gas, providing a high-efficiency, cost-effective, and environmentally friendly solution for the treatment of multi-pollutants in flue gases.