Synthesis, Structures, and Aggregation-Induced Emission Properties of Distyrylbenzene Derivatives Containing Fluorine
Daisuke Furusho1, Naoki Shida2, Ryoyu Hifumi1
1Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan.
Abstract:
Distyrylbenzene derivatives with substituents on the vinylene moieties have been studied due to interest in their optoelectronic properties. In this study, we focused on distyrylbenzene derivatives with monofluoroolefin structures, expecting intermolecular H-F interactions in the solid state. UV-vis and fluorescence spectra of the obtained compounds were measured and compared with those of unsubstituted distyrylbenzene. The crystal structures of each compound were determined by single crystal X-ray diffraction and Hirshfeld surface analysis to understand the intermolecular contacts.
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