9-Azahomocubane

Tyler Fahrenhorst-Jones1, David L Marshall2, Jed M Burns1

  • 1School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, 4072, Queensland, Australia.

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Azide ions act as good nucleophiles and react with unhindered alkyl halides to form alkyl azides. Alkyl azides do not participate in further nucleophilic substitution reactions, thereby eliminating the chances of polyalkylated products. Alkyl azides are reduced by hydride-based reducing agents, like lithium aluminum...
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