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Updated: Jul 13, 2025
11:27
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Dynamic and transformable Cu12 cluster-based C-H···π-stacked porous supramolecular frameworks.
Chengkai Zhang1, Zhi Wang1, Wei-Dan Si1
1School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan, 250100, People's Republic of China.
Nature Communications
|October 12, 2023
Summary
Researchers developed a novel porous supramolecular framework using copper nanoclusters. This material efficiently captures iodine from water, demonstrating its potential for environmental applications.
Area of Science:
- Materials Science
- Supramolecular Chemistry
- Nanotechnology
Background:
- Assembling cluster-based π-stacked porous supramolecular frameworks is challenging.
- Key challenges include cluster design, C-H···π interactions, and stability-property trade-offs.
Purpose of the Study:
- To report a novel cluster-based C-H···π interaction-stacked porous supramolecular framework.
- To investigate its properties and potential applications, such as iodine removal.
Main Methods:
- Utilized Cu12 nanoclusters as 6-connected nodes.
- Propagated framework via intralayer C-H···π interactions.
- Investigated ligand-exchange for transformation into nonporous adaptive crystals.
Main Results:
- Synthesized Cu12a-π, a dynamic porous supramolecular framework with permanent porosity.
- Demonstrated efficient iodine removal (97.2%) from aqueous solutions.
- Achieved a high iodine uptake capacity of 2.96 g·g⁻¹.
Conclusions:
- The developed framework offers a promising platform for designing advanced porous materials.
- Highlights the potential of C-H···π interactions in creating functional supramolecular structures.
- Provides insights for future research in cluster-based porous materials for environmental remediation.
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