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Constructing a carboxyl-rich angstrom-level trap in a metal-organic framework for the selective capture of lithium

Xinxin Gao1, Rui Ding1, Hongliang Huang2

  • 1College of Chemical Engineering and Technology, Taiyuan University of Science and Technology, Taiyuan 030024, China. zhaoxd@tyust.edu.cn.

Chemical Communications (Cambridge, England)
|October 18, 2023
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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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