Environmental behavior of silver nanomaterials in aquatic environments: An updated review

The increasing applications of silver nanomaterials (nano-Ag) and their inevitable release posed great potential risks to aquatic organisms and ecosystems. Considerable attention has been attracted on their behaviors and transformations, which were critically important for their subsequent biological toxicities and ecological effects. Therefore, the summary of the recent efforts on the environmental behavior of nano-Ag would be beneficial for understanding the environmental fate and accurate risk assessment. This review summarized the studies on various physical, chemical and biological transformations of nano-Ag, meanwhile, the influencing factors (including the intrinsic properties and environmental conditions) and related mechanisms were highlighted. Surface structure and facets of nano-Ag, abiotic conditions and natural freeze-thaw cycle processes could affect the transformations of nano-Ag under different environmental scenarios (including freshwater, seawater and wastewater). The interactions with co-present components, such as chemicals and other particles, impacted the multiple processes of nano-Ag. Besides, the contradictory effects and mechanisms by several environmental factors were summarized. Lastly, the key knowledge gaps and some aspects that deserve further investigation were also addressed. Therefore, the current review aimed to provide an overall analysis of transformation processes of nano-Ag, which will provide more available information and pave the way for the future research areas.