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Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
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Phase transitions play an important theoretical and practical role in the study of heat flow. In melting or fusion, a solid turns into a liquid; the opposite process is freezing. In evaporation, a liquid turns into a gas; the opposite process is condensation.
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The phase of a given substance depends on the pressure and temperature. Thus, plots of pressure versus temperature showing the phase in each region provide considerable insights into the thermal properties of substances. Such plots are known as phase diagrams. For instance, in the phase diagram for water (Figure 1), the solid curve boundaries between the phases indicate phase transitions (i.e., temperatures and pressures at which the phases coexist).
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The internal energy of a substance—the total kinetic energy of all its molecules and the potential energy of their associated forces—depends on the strength of the intermolecular forces in the condensed phases and the pressure exerted on the substance. The internal energy of a substance is the highest in the gaseous state, the lowest in the solid state, and intermediate in the liquid state. Phase transitions are caused by changes in physical conditions, such as temperature and...
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Electromagnetic waves can travel in the vacuum as well as in matter. For example light, which is an electromagnetic wave, can travel through air, water, or glass.
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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
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Roadmap for phase change materials in photonics and beyond.

Patinharekandy Prabhathan1,2, Kandammathe Valiyaveedu Sreekanth3, Jinghua Teng3

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Phase Change Materials (PCMs) enable reconfigurable micro-nanophotonic devices across the electromagnetic spectrum. This review covers PCM materials, devices, and applications from terahertz to visible frequencies.

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Area of Science:

  • Optoelectronics
  • Materials Science
  • Nanotechnology

Background:

  • Phase Change Materials (PCMs) are crucial for advanced micro-nanophotonic devices.
  • PCMs offer tunable functionalities across terahertz to visible frequencies.
  • Reconfigurable photonic devices require novel material platforms.

Purpose of the Study:

  • To provide a comprehensive roadmap of Phase Change Materials in micro-nanophotonics.
  • To review material and device aspects of PCMs for photonic applications.
  • To explore diverse applications and future directions for PCMs.

Main Methods:

  • Review of existing literature on PCMs in photonics.
  • Analysis of material properties and device configurations.
  • Discussion of optimization techniques, including deep learning-based metasurface design.

Main Results:

  • PCMs facilitate active and reconfigurable photonic devices.
  • Integration with Photonic Integrated Circuits and electric-driven PCMs are key advancements.
  • Deep learning enhances metasurface design for PCMs.

Conclusions:

  • PCMs are pivotal for multifunctional photonic devices.
  • Promising applications include non-volatile memory, optical data storage, and neuromorphic computing.
  • PCMs are essential for future innovations in photonics, energy, and electronics.