Cellulose nanocrystals reinforced chitosan/titanium dioxide bionanocomposite with enhanced interfacial compatibility:...

This research aimed to investigate the feasibility of using a bionanocomposite made of chitosan, CNC, and TiO2 nanoparticles to package freshly sliced apples. At the outset, the effect of varying concentrations of CNC (1, 5, and 10 %) and TiO₂ (1, 3, and 5 %) on the mechanical, thermal, and water sensitivity characteristics of the chitosan bionanocomposite was studied. Among different combinations, the bionanocomposite containing 10 % CNC and 3 % TiO₂ displayed significant enhancements compared to neat chitosan film. Notably, it exhibited a substantial increase in tensile strength (78.2 %), glass transition temperature (26.7 %), and melting temperature (30.0 %) compared to neat chitosan film. Additionally, it demonstrated reduced WVP (27.8 %), FWS (44.4 %), and SR (50.7 %). These improvements were attributed to the synergistic interactions among chitosan, CNC, and TiO₂ nanoparticles through hydrogen and oxygen bonding, corroborated by spectral changes in the material. The photocatalytic degradation of ethylene and microbes by UV-A (intermittent) activated TiO₂ contained in the developed bionanocomposite was confirmed by the retention of acceptable quality and radical scavenging activity (70 % retention) of fresh-cut apple slices up to 11 days. The developed bionanocomposite can thus preserve the quality of ethylene-producing horticultural produce.