Dual-responsive colloidosome-like microgels as the building blocks for phase inversion of Pickering emulsions

The intelligent regulation of microgel-stabilized Pickering emulsions with multi-responsiveness is presently constrained to the processes of emulsification and destabilization. However, the expansion of multi-control over Pickering emulsions to involve phase inversion and the investigation of the accompanying processes and mechanisms present a great challenge. In this study, a microgel with dual responsiveness to both pH and temperature was synthesized using an emulsion template. The resulting microgel exhibited a robust colloidosome-like structure, distinguished by the presence of monolayer-adsorbed silica nanoparticles. The regulation of the packing of surface-covered silica nanoparticles was easily achieved through the swelling of the microgel matrix. Furthermore, the wettability of the microgel can be adjusted between hydrophilic and hydrophobic intervals, allowing for the effective and dual-responsive phase inversion of Pickering emulsions. Moreover, it has been observed that colloidosome-like microgels can lead to unique interfacial structures during the emulsification process, thereby elucidating the fundamental mechanism governing emulsion phase inversion.