pH-Responsive swimming behavior of light-powered rod-shaped micromotors

Micromotors have emerged as promising devices for a wide range of applications e.g., microfluidics, lab-on-a-chip devices, active matter, environmental monitoring, etc. The control over the activity of micromotors with the ability to exhibit multimode swimming is one of the most desirable features for many of the applications. Here, we demonstrate a rod-shaped light-driven micromotor whose activity and swimming behavior can easily be controlled. The rod-shaped micromotors are fabricated through the dynamic shadowing growth (DSG) technique, where a 2 μm long arm of titanium dioxide (TiO₂) is grown over spherical silica (SiO₂) particles (1 μm diameter). Under low-intensity UV light exposure, the micromotors exhibit self-propulsion in an aqueous peroxide medium. When activated, the swimming behavior of micromotors greatly depends on the pH of the medium. The swimming direction, i.e., forward or backward movement, as well as swimming modes like translational or rotational motion, can be controlled by changing the pH values. The observed dynamics has been rationalized using a theoretical model incorporating chemical activity, hydrodynamic flow, and the effect of gravity for a rod-shaped active particle near a planar wall. The pH-dependent translational and rotational dynamics of micromotors provide a versatile platform for achieving controlled and responsive behaviors. Continued research and development in this area hold great promise for advancing micromotors and enabling novel applications in microfluidics, micromachining, environmental sciences, and biomedicine.