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Related Concept Videos

Photoluminescence: Applications01:14

Photoluminescence: Applications

410
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
410

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Related Experiment Video

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Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection
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Smart-Responsive HOF Heterostructures with Multiple Spatial-Resolved Emission Modes toward Photonic Security

Yuanchao Lv1, Jiashuai Liang1, Zhile Xiong1

  • 1Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China.

Advanced Materials (Deerfield Beach, Fla.)
|October 25, 2023
PubMed
Summary

Researchers developed smart-responsive hydrogen-bonded organic frameworks (HOFs) heterostructures. These novel materials offer enhanced security for anticounterfeiting applications through dynamic, multi-modal photonic barcodes.

Keywords:
anticounterfeitingepitaxial growthhydrogen-bonded organic frameworkoptical heterostructurestimuli response

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Area of Science:

  • Materials Science
  • Organic Chemistry
  • Photonic Security

Background:

  • Luminescent hydrogen-bonded organic frameworks (HOFs) show promise for information security due to their dynamic nature and functional sites.
  • Current responsive HOFs often lack emission control, limiting their use in advanced confidential information protection.

Purpose of the Study:

  • To report the first smart-responsive HOF heterostructure with multiple spatial-resolved emission modes for covert photonic security.
  • To demonstrate a novel approach for advanced anticounterfeiting applications using HOF microdevices.

Main Methods:

  • Fabrication of HOF heterostructures by integrating different HOFs into a single microwire.
  • Utilizing a hydrogen-bond-assisted epitaxial growth method for heterostructure assembly.
  • Investigating dual stimuli-responsive behaviors (thermochromism and acidichromism) for emission control.

Main Results:

  • The HOF heterostructures exhibit simultaneous thermochromism and acidichromism, leading to multiple emission modes.
  • Dual stimuli-controlled spatial-resolved emissions create a unique fingerprint for each heterostructure.
  • Demonstrated the creation of smart-responsive photonic barcodes with multiple convertible states.

Conclusions:

  • The developed HOF heterostructures enable dynamic coding capabilities for enhanced security in anticounterfeiting.
  • This work provides a promising strategy for designing function-oriented, smart-responsive HOF microdevices.
  • The findings pave the way for advanced photonic security platforms and anticounterfeiting technologies.