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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Hexa- and octanuclear copper(II) complexes with a tetraeicosaaza amine macrocycle
Dominika Fedorowicz1, Katarzyna Ślepokura1, Julia Kłak1
1Faculty of Chemistry, Wroclaw University, F. Joliot-Curie 14, 50-283 Wroclaw, Poland. janusz.gregolinski@uwr.edu.pl.
Abstract:
One hexa- and two octanuclear Cu(II) complexes were synthesised from different metal salts and a very large (8 + 8) tetraeicosaaza macrocycle. These nitrate, chloride and sulphate coordination compounds were characterised by taking elemental analysis, spectroscopy, crystallography and magnetic susceptibility measurements. Their crystal structures revealed different interesting coordination modes of Cu(II) cations and nuclearity in these centrosymmetric complexes. For the sulphate complex two different, homo- vs. heterochiral, arrangements of the same macrocycle L3 around the same Cu(II) cations take place.
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